Netherlands Institute for Conservation, Art and Science

Predicting aging of oil networks

Little is known about the intrinsic instability of oil paintings. It can become manifest by visual damage, a possible warning sign for more dramatic deterioration in the future. Damage such a protrusions or discolorations is often caused by the formation of metal soaps, compounds of metals with fatty acids. Oil paintings are essentially thermodynamically unstable systems developing towards more stable, but aesthetically less attractive, states. Analyzed paint samples prove that metal is displaced across the paint film in this process, but the exact role of the linseed oil networks used as binding medium is unclear. This project aims to better understand the behavior of metal in linseed oil networks by gaining more information about the microstructure of the latter. It will use multi-scale mathematical modeling to predict this microstructure in the various states of an oil painting, from the process of applying the paint through the drying stage until highly degraded conditions. The models will answer questions about the extent to which higher temperatures and relative humidity and the ranges of fluctuations in both promote degradation of pigments in oil paintings. This information is crucial in making informed decisions about safe display and storage conditions.

Piet Iedema

The drying of linseed oil as a binding medium (left) leads to a 3D polymer network (right).

Project acronym

PREDAGIO

Principal investigator

  • Prof. dr. P.D. Iedema (University of Amsterdam)

 

Co-Principal investigators

  • Dr. K.J. van den Berg (Cultural Heritage Agency of the Netherlands)
  • Dr. K. Keune (Rijksmuseum, University of Amsterdam)
  • Dr. A. van Loon (University of Amsterdam, Delft University of Technology)
  • Dr. ir. H.L. Schellen (Eindhoven University of Technology)
  • Dr. M.J.N. Stols-Witlox (University of Amsterdam)
  • Prof. dr. A. Suiker (Eindhoven University of Technology

Research team

  • Dr. B. Ankersmit (Cultural Heritage Agency of the Netherlands)
  • Prof. dr. P. Bolhuis (University of Amsterdam)
  • P. van Duin (Rijksmuseum)
  • Dr. M. van Eikema Hommes (Cultural Heritage Agency of the Netherlands, Delft University of Technology)
  • Drs. P. Noble (Rijksmuseum)
  • Prof. dr. P. Schoenmakers (University of Amsterdam)
  • B. Schoonhoven

Participating institutions

  • Cultural Heritage Agency of the Netherlands
  • Delft University of Technology
  • Eindhoven University of Technology
  • Rijksmuseum
  • University of Amsterdam

Want to know more?

Please click here for project updates and background information.

Published by  NICAS

6 April 2017